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Small-molecular mass porphyrins in which a carboxylic acid group replaces the chlorine atom in TPPH have been prepared. The molecular masses of these compounds were determined by mass spectroscopy, and their structure was confirmed by single-crystal X-ray diffraction. The porphyrins have been used to determine the excitation spectra of TPPH and its isomeric porphyrins.
Spectral measurements were performed by flash photolysis, steady-state absorption, and steady-state fluorescence. The excitation spectra of all the porphyrins form a continuum, with the fluorescence maximized at approximately nm.
The fluorescence quantum yield of TPPH was determined to be approximately 0. The significance of these results is that they demonstrate that structural modification of the axial ligand of the porphyrin ring can shift both the emission and the absorption spectra.
I have been trying to secure materials to make a sprocket out of stainless steel, and just cant get a pattern to come out the way i want it to. I have tried going to parkson and looking at the patterns, but none of them seem to work out as they wont line up on the sprocket wheel.
I have also been looking at ways to make the sprocket. I would like to make one out of steel but have also looked into making a steel one out of toothed wheel, it would be called a toothed wheel sprocket.
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